eprintid: 10094167
rev_number: 14
eprint_status: archive
userid: 608
dir: disk0/10/09/41/67
datestamp: 2020-03-30 09:52:08
lastmod: 2021-09-20 22:38:24
status_changed: 2020-03-30 09:52:08
type: article
metadata_visibility: show
creators_name: Frei, A
creators_name: Zuegg, J
creators_name: Elliott, AG
creators_name: Baker, M
creators_name: Braese, S
creators_name: Brown, C
creators_name: Chen, F
creators_name: G Dowson, C
creators_name: Dujardin, G
creators_name: Jung, N
creators_name: King, AP
creators_name: Mansour, AM
creators_name: Massi, M
creators_name: Moat, J
creators_name: Mohamed, HA
creators_name: Renfrew, AK
creators_name: Rutledge, PJ
creators_name: Sadler, PJ
creators_name: Todd, MH
creators_name: Willans, CE
creators_name: Wilson, JJ
creators_name: Cooper, MA
creators_name: Blaskovich, MAT
title: Metal complexes as a promising source for new antibiotics
ispublished: pub
divisions: UCL
divisions: B02
divisions: C08
divisions: D10
divisions: G09
note: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/)
abstract: There is a dire need for new antimicrobial compounds to combat the growing threat of widespread antibiotic resistance. With a currently very scarce drug pipeline, consisting mostly of derivatives of known antibiotics, new classes of antibiotics are urgently required. Metal complexes are currently in clinical development for the treatment of cancer, malaria and neurodegenerative diseases. However, only little attention has been paid to their application as potential antimicrobial compounds. We report the evaluation of 906 metal-containing compounds that have been screened by the Community for Open Antimicrobial Drug Discovery (CO-ADD) for antimicrobial activity. Metal-bearing compounds display a significantly higher hit-rate (9.9%) when compared to the purely organic molecules (0.87%) in the CO-ADD database. Out of 906 compounds, 88 show activity against at least one of the tested strains, including fungi, while not displaying any cytotoxicity against mammalian cell lines or haemolytic properties. Herein, we highlight the structures of the 30 compounds with activity against Gram-positive and/or Gram-negative bacteria containing Mn, Co, Zn, Ru, Ag, Eu, Ir and Pt, with activities down to the nanomolar range against methicillin resistant S. aureus (MRSA). 23 of these complexes have not been reported for their antimicrobial properties before. This work reveals the vast diversity that metal-containing compounds can bring to antimicrobial research. It is important to raise awareness of these types of compounds for the design of truly novel antibiotics with potential for combatting antimicrobial resistance.
date: 2020-03-14
date_type: published
official_url: http://dx.doi.org/10.1039/c9sc06460e
oa_status: green
full_text_type: pub
pmcid: PMC7069370
language: eng
primo: open
primo_central: open_green
verified: verified_manual
elements_id: 1774128
doi: 10.1039/c9sc06460e
pii: c9sc06460e
lyricists_name: Todd, Matthew
lyricists_id: MTODD88
actors_name: Wong, Ian
actors_name: Harris, Jean
actors_id: ICKWO00
actors_id: JAHAR68
actors_role: owner
actors_role: impersonator
full_text_status: public
publication: Chemical Science
volume: 11
number: 10
pagerange: 2627-2639
event_location: England
citation:        Frei, A;    Zuegg, J;    Elliott, AG;    Baker, M;    Braese, S;    Brown, C;    Chen, F;                                                                 ... Blaskovich, MAT; + view all <#>        Frei, A;  Zuegg, J;  Elliott, AG;  Baker, M;  Braese, S;  Brown, C;  Chen, F;  G Dowson, C;  Dujardin, G;  Jung, N;  King, AP;  Mansour, AM;  Massi, M;  Moat, J;  Mohamed, HA;  Renfrew, AK;  Rutledge, PJ;  Sadler, PJ;  Todd, MH;  Willans, CE;  Wilson, JJ;  Cooper, MA;  Blaskovich, MAT;   - view fewer <#>    (2020)    Metal complexes as a promising source for new antibiotics.                   Chemical Science , 11  (10)   pp. 2627-2639.    10.1039/c9sc06460e <https://doi.org/10.1039/c9sc06460e>.       Green open access   
 
document_url: https://discovery.ucl.ac.uk/id/eprint/10094167/1/c9sc06460e.pdf