eprintid: 10082709 rev_number: 27 eprint_status: archive userid: 608 dir: disk0/10/08/27/09 datestamp: 2019-10-03 11:47:03 lastmod: 2021-09-25 23:22:21 status_changed: 2020-06-10 10:55:36 type: article metadata_visibility: show creators_name: Pallares, RM creators_name: Thanh, NTK creators_name: Su, X title: Sensing of circulating cancer biomarkers with metal nanoparticles ispublished: pub divisions: UCL divisions: B04 divisions: C06 divisions: F60 note: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. https://creativecommons.org/licenses/by/3.0/ abstract: The analysis of circulating cancer biomarkers, including cell-free and circulating tumor DNA, circulating tumor cells, microRNA and exosomes, holds promise in revolutionizing cancer diagnosis and prognosis using body fluid analysis, also known as liquid biopsy. To enable clinical application of these biomarkers, new analytical tools capable of detecting them in very low concentrations in complex sample matrixes are needed. Metal nanoparticles have emerged as extraordinary analytical scaffolds because of their unique optoelectronic properties and ease of functionalization. Hence, multiple analytical techniques have been developed based on these nanoparticles and their plasmonic properties. The aim of this review is to summarize and discuss the present development on the use of metal nanoparticles for the analysis of circulating cancer biomarkers. We examine how metal nanoparticles can be used as (1) analytical transducers in various sensing principles, such as aggregation induced colorimetric assays, plasmon resonance energy transfer, surface enhanced Raman spectroscopy, and refractive index sensing, and (2) signal amplification elements in surface plasmon resonance spectroscopy and electrochemical detection. We critically discuss the clinical relevance of each category of circulating biomarkers, followed by a thorough analysis of how these nanoparticle-based designs have overcome some of the main challenges that gold standard analytical techniques currently face, and what new directions the field may take in the future. date: 2019-12-14 date_type: published official_url: https://doi.org/10.1039/c9nr03040a oa_status: green full_text_type: pub language: eng primo: open primo_central: open_green verified: verified_manual elements_id: 1697663 doi: 10.1039/c9nr03040a lyricists_name: Nguyen, Thanh lyricists_id: TTKNG00 actors_name: Flynn, Bernadette actors_id: BFFLY94 actors_role: owner full_text_status: public publication: Nanoscale volume: 11 number: 46 pagerange: 22152-22171 event_location: England issn: 2040-3372 citation: Pallares, RM; Thanh, NTK; Su, X; (2019) Sensing of circulating cancer biomarkers with metal nanoparticles. Nanoscale , 11 (46) pp. 22152-22171. 10.1039/c9nr03040a <https://doi.org/10.1039/c9nr03040a>. Green open access document_url: https://discovery.ucl.ac.uk/id/eprint/10082709/7/Nguyen_c9nr03040a.pdf