eprintid: 10078664 rev_number: 23 eprint_status: archive userid: 608 dir: disk0/10/07/86/64 datestamp: 2019-07-24 09:59:28 lastmod: 2021-10-05 00:33:10 status_changed: 2019-07-24 09:59:28 type: article metadata_visibility: show creators_name: Leng, L creators_name: Bogush, AA creators_name: Roy, A creators_name: Stegemann, JA title: Characterisation of ashes from waste biomass power plants and phosphorus recovery ispublished: pub divisions: UCL divisions: B04 divisions: C05 divisions: F44 keywords: Incineration, Fertiliser, Phosphorus recovery, Acid neutralization capacity, Animal manure note: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. abstract: Biowastes, such as meat and bone meal (MBM), and poultry litter (PL), are used as energy sources for industrial combustion in the UK. However, the biomass ashes remaining after combustion, which contain nutrients such as phosphorus, are landfilled rather than utilised. To promote their utilisation, biomass ashes from industries were characterised in terms of their elemental and mineral compositions, phosphorus extractability, and pH-dependent leachability. These ashes were highly alkaline (pH as high as 13), and rich in calcium and phosphorus. The P bio-availabilities in the ash evaluated by Olsen's extraction were low. Hydroxyapatite and potassium sodium calcium phosphate were identified by X-ray powder diffraction (XRD) as the major phases in the MBM and PL ashes, respectively. The leaching of P, Ca, and many other elements was pH dependent, with considerable increase in leaching below about pH 6. P recovery by acid dissolution (e.g., with H2SO4) seems feasible and promising; the optimized acid consumption for ~90% P recovery could be as low as 3.2–5.3 mol H+/mol P. date: 2019-11-10 date_type: published official_url: https://doi.org/10.1016/j.scitotenv.2019.06.312 oa_status: green full_text_type: other language: eng primo: open primo_central: open_green article_type_text: Journal Article verified: verified_manual elements_id: 1673638 doi: 10.1016/j.scitotenv.2019.06.312 lyricists_name: Bogush, Anna lyricists_name: Stegemann, Julia lyricists_id: ABOGU43 lyricists_id: JSTEG94 actors_name: Stegemann, Julia actors_id: JSTEG94 actors_role: owner full_text_status: public publication: Science of the Total Environment volume: 690 pagerange: 573-583 issn: 1879-1026 citation: Leng, L; Bogush, AA; Roy, A; Stegemann, JA; (2019) Characterisation of ashes from waste biomass power plants and phosphorus recovery. Science of the Total Environment , 690 pp. 573-583. 10.1016/j.scitotenv.2019.06.312 <https://doi.org/10.1016/j.scitotenv.2019.06.312>. Green open access document_url: https://discovery.ucl.ac.uk/id/eprint/10078664/8/Stegemann%20STOTEN-D-19-07294R1.pdf