<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> . <> <http://xmlns.com/foaf/0.1/primaryTopic> <https://discovery.ucl.ac.uk/id/eprint/10074520> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/AcademicArticle> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/title> "Co-electrospraying of tumour cell mimicking hollow polymeric microspheres for diffusion magnetic resonance imaging"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/abstract> "Diffusion magnetic resonance imaging (dMRI) is considered as a useful tool to study solid tumours. However, the interpretation of dMRI signal and validation of quantitative measurements of is challenging. One way to address these challenges is by using a standard reference material that can mimic tumour cell microstructure. There is a growing interest in using hollow polymeric microspheres, mainly prepared by multiple steps, as mimics of cells in healthy and diseased tissue. The present work reports on tumour cell-mimicking materials composed of hollow microspheres for application as a standard material in dMRI. These microspheres were prepared via one-step co-electrospraying process. The shell material was poly(d,l-lactic-co-glycolic acid) (PLGA) polymers with different molecule weights and/or ratios of glycolic acid-to-lactic, while the core was polyethylene glycol (PEG) or ethylene glycol. The resultant co-electrosprayed products were characterised by optical microscopy, scanning electron microscopy (SEM) and synchrotron X-ray micro-CT. These products were found to have variable structures and morphologies, e.g. from spherical particles with/without surface hole, through beaded fibres to smooth fibres, which mainly depend on PLGA composition and core materials. Only the shell material of PLGA polymer with ester terminated, Mw 50,000-75,000 g mol-1, and lactide:glycolide 85:15 formed hollow microspheres via the co-electrospraying process using the core material of 8 wt% PEG/chloroform as the core. A water-filled test object (or phantom) was designed and constructed from samples of the material generated from co-electrosprayed PLGA microspheres and tested on a 7 T MRI scanner. The preliminary MRI results provide evidence that hollow PLGA microspheres can restrict/hinder water diffusion as cells do in tumour tissue, implying that the phantom may be suitable for use as a quantitative validation and calibration tool for dMRI."^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/date> "2019-08" . <https://discovery.ucl.ac.uk/id/document/903325> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Document> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/volume> "101" . <https://discovery.ucl.ac.uk/id/publication/ext-18730191> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Collection> . <https://discovery.ucl.ac.uk/id/publication/ext-18730191> <http://xmlns.com/foaf/0.1/name> "Materials Science and Engineering: C"^^<http://www.w3.org/2001/XMLSchema#string> . 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<https://discovery.ucl.ac.uk/id/person/ext-6b0d0d6c9ed985aebb9f715b2b31b2c6> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_2> <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_3> <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_4> <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_5> <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_6> <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_7> <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> . <https://discovery.ucl.ac.uk/id/eprint/10074520#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_8> <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> . <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> <http://xmlns.com/foaf/0.1/givenName> "PL"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> <http://xmlns.com/foaf/0.1/familyName> "Hubbard Cristinacce"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-4ee9888071fecedf0f7fd36869d85281> <http://xmlns.com/foaf/0.1/name> "PL Hubbard Cristinacce"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> <http://xmlns.com/foaf/0.1/givenName> "X"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> <http://xmlns.com/foaf/0.1/familyName> "Zhang"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ac8c519f9c2fe85d6347c187d7b81c71> <http://xmlns.com/foaf/0.1/name> "X Zhang"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6b0d0d6c9ed985aebb9f715b2b31b2c6> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-6b0d0d6c9ed985aebb9f715b2b31b2c6> <http://xmlns.com/foaf/0.1/givenName> "F-L"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6b0d0d6c9ed985aebb9f715b2b31b2c6> <http://xmlns.com/foaf/0.1/familyName> "Zhou"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6b0d0d6c9ed985aebb9f715b2b31b2c6> <http://xmlns.com/foaf/0.1/name> "F-L Zhou"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> <http://xmlns.com/foaf/0.1/givenName> "DJ"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> <http://xmlns.com/foaf/0.1/familyName> "McHugh"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fc33cf94ec083d123c2016bca00b3458> <http://xmlns.com/foaf/0.1/name> "DJ McHugh"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> <http://xmlns.com/foaf/0.1/givenName> "H"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> <http://xmlns.com/foaf/0.1/familyName> "Wu"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8ed2e7009ef69fc43df926e372fcbc07> <http://xmlns.com/foaf/0.1/name> "H Wu"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> <http://xmlns.com/foaf/0.1/givenName> "GJM"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> <http://xmlns.com/foaf/0.1/familyName> "Parker"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-910f9ece2ecfb0064fd903ac94772e38> <http://xmlns.com/foaf/0.1/name> "GJM Parker"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> <http://xmlns.com/foaf/0.1/givenName> "JE"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> <http://xmlns.com/foaf/0.1/familyName> "Gough"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-57add6fc36c97f03a3a7ca9248adb627> <http://xmlns.com/foaf/0.1/name> "JE Gough"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> <http://xmlns.com/foaf/0.1/givenName> "I"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> <http://xmlns.com/foaf/0.1/familyName> "Wimpenny"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8452477de4b683926b701e594b5ee9f3> <http://xmlns.com/foaf/0.1/name> "I Wimpenny"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://eprints.org/ontology/EPrint> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://eprints.org/ontology/ArticleEPrint> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://purl.org/dc/terms/isPartOf> <https://discovery.ucl.ac.uk/id/repository> . <https://discovery.ucl.ac.uk/id/eprint/10074520> <http://eprints.org/ontology/hasDocument> <https://discovery.ucl.ac.uk/id/document/903325> . <https://discovery.ucl.ac.uk/id/document/903325> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://eprints.org/ontology/Document> . <https://discovery.ucl.ac.uk/id/document/903325> <http://www.w3.org/2000/01/rdf-schema#label> "Co-electrospraying of tumour cell mimicking hollow polymeric microspheres for diffusion magnetic resonance imaging (Text)"^^<http://www.w3.org/2001/XMLSchema#string> . 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