eprintid: 10062414
rev_number: 23
eprint_status: archive
userid: 608
dir: disk0/10/06/24/14
datestamp: 2018-11-27 15:04:29
lastmod: 2021-09-27 22:32:00
status_changed: 2018-11-30 11:48:04
type: article
metadata_visibility: show
creators_name: Di Lecce, D
creators_name: Andreotti, P
creators_name: Boni, M
creators_name: Gasparro, G
creators_name: Rizzati, G
creators_name: Hwang, J-Y
creators_name: Sun, Y-K
creators_name: Hassoun, J
title: Multiwalled Carbon Nanotubes Anode in Lithium-Ion Battery with LiCoO₂, Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O₂, and LiFe_{1/4}Mn_{1/2}Co_{1/4}PO₄ Cathodes
ispublished: pub
divisions: UCL
divisions: B04
divisions: C05
divisions: F43
keywords: Li-ion battery, LiCoO₂, LiFe_{1/4}Mn_{1/2}Co_{1/4}PO₄, Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O₂, Multiwalled carbon
note: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
abstract: Multiwalled carbon nanotubes (MWCNTs) are studied for the first time as the anode in lithium-ion batteries using LiCoO₂, Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O₂, and LiFe_{1/4}Mn_{1/2}Co_{1/4}PO₄ cathodes. The anode material has a partially graphitic structure and nanotube morphology, which ensure stable cycling, Coulombic efficiency exceeding 99% as well as remarkable rate-capability in lithium half-cell, and suggest the compatibility for full-cell application. The performance of each lithium-ion array appears strongly related to the different structural, morphological and electrochemical features of the positive electrodes. The study in full-cell of the MWCNTs anode, to date mostly investigated in lithium half-cell, is therefore performed under various conditions. The MWCNTs/Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O₂ combination reveals promising behavior in terms of cycling stability, reversible capacity and Coulombic efficiency, which well demonstrates the potential suitability of MWCNTs as anodes in lithium-ion cell.
date: 2018-03-05
date_type: published
publisher: AMER CHEMICAL SOC
official_url: http://dx.doi.org/10.1021/acssuschemeng.7b03395
oa_status: green
full_text_type: other
language: eng
primo: open
primo_central: open_green
article_type_text: Journal Article
verified: verified_manual
elements_id: 1589042
doi: 10.1021/acssuschemeng.7b03395
language_elements: English
lyricists_name: Di Lecce, Daniele
lyricists_id: DDILE26
actors_name: Di Lecce, Daniele
actors_id: DDILE26
actors_role: owner
full_text_status: public
publication: ACS Sustainbale Chemistry & Engineering
volume: 6
number: 3
pagerange: 3225-3232
pages: 15
issn: 2168-0485
citation:        Di Lecce, D;    Andreotti, P;    Boni, M;    Gasparro, G;    Rizzati, G;    Hwang, J-Y;    Sun, Y-K;           Di Lecce, D;  Andreotti, P;  Boni, M;  Gasparro, G;  Rizzati, G;  Hwang, J-Y;  Sun, Y-K;  Hassoun, J;   - view fewer <#>    (2018)    Multiwalled Carbon Nanotubes Anode in Lithium-Ion Battery with LiCoO₂, Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O₂, and LiFe_{1/4}Mn_{1/2}Co_{1/4}PO₄ Cathodes.                   ACS Sustainbale Chemistry & Engineering , 6  (3)   pp. 3225-3232.    10.1021/acssuschemeng.7b03395 <https://doi.org/10.1021/acssuschemeng.7b03395>.       Green open access   
 
document_url: https://discovery.ucl.ac.uk/id/eprint/10062414/1/Di%20Lecce_Multiwalled%20Carbon%20Nanotubes%20Anode%20in%20Lithium-Ion%20Battery%20with%20LiCoO%E2%82%82%2C%20Li%5BNi_%7B13%7DCo_%7B13%7DMn_%7B13%7D%5DO%E2%82%82%2C%20and%20LiFe_%7B14%7DMn_%7B12%7DCo_%7B14%7DPO%E2%82%84%20Cathodes_AAM.pdf