GUNNING, J;
NEIDLE, S;
MILLICAN, T;
EATON, M;
MOCK, G;
MANN, J;
(1985)
THE STRUCTURE OF 3,5-DI-O-BENZOYL-1,2-DIDEOXY-1-PHENYL-BETA-D-RIBOFURANOSE, C25H22O5.
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
, 41
(Part 5)
720 - 722.
10.1107/S010827018500525X.
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Abstract
Mr=402.4, orthorhombic, P212~2 l, a= 4-946 (1), b= 15.887 (2), c=26.555 (2)A, V= 2086.7 (5) A 3, Z = 4, D x = 1.28 gcm -a, Cu Ka, 2 = 1.5418/k, B = 6.868 cm -1, F(000) = 848, T= 293 K, final R =0.054 for 648 observed reflections. The molecule is propeller shaped. The benzoyl groups act as protecting groups and the phenyl group is a base substitute. The crystal structure does not involve any intermolecular stacking interactions between the phenyl groups. The molecules pack in typical herring-bone-like arrays. The sugar has a fl-D configuration with C(2')-endo-C(3')-exo pucker (2T3), pseudorotation angle P = 172 (2) °, degree of pucker r m = 39 (2) °.
| Type: | Article |
|---|---|
| Title: | THE STRUCTURE OF 3,5-DI-O-BENZOYL-1,2-DIDEOXY-1-PHENYL-BETA-D-RIBOFURANOSE, C25H22O5 |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1107/S010827018500525X |
| Publisher version: | http://scripts.iucr.org/cgi-bin/paper?S01082701850... |
| Language: | English |
| Additional information: | Copyright © International Union of Crystallography |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1367887 |
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