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Some intermolecular Pauson-Khand reactions of functionalised alkylidenecyclopropanes

Corlay, H; James, IW; Fouquet, E; Schmidt, J; Motherwell, WB; (1996) Some intermolecular Pauson-Khand reactions of functionalised alkylidenecyclopropanes. SYNLETT (10) 990 - &.

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Abstract

Functionalised alkylidenecyclopropanes undergo efficient intermolecular Pauson-Khand reactions to give bi- and tricyclic skeletons with preservation of a spirocyclic cyclopropyl unit. The observed regio- and stereoselectivities are, in part, determined by the nature of these substituents.

Type:Article
Title:Some intermolecular Pauson-Khand reactions of functionalised alkylidenecyclopropanes
Keywords:functionalised alkylidenecyclopropanes, intermolecular Pauson-Khand reaction, CATALYZED 3+2 CYCLOADDITIONS, N-OXIDE, METHYLENECYCLOPROPANES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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