BATEY, RA and MOTHERWELL, WB (1991) SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES. TETRAHEDRON LETT , 32 (45) 6649 - 6652.
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Abstract
Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy. The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.
| Type: | Article |
|---|---|
| Title: | SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES |
| Keywords: | SAMARIUM(II) IODIDE REDUCTION, CYCLOPROPYLCARBINYL RADICAL REARRANGEMENT, CYCLOPROPYL KETONE, RADICAL CYCLIZATION, SAMARIUM ENOLATE, ORGANIC-SYNTHESIS, CHAIN REACTIONS, CYCLIZATION, LANTHANIDES, CHEMISTRY, DESIGN |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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