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SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES

BATEY, RA; MOTHERWELL, WB; (1991) SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES. TETRAHEDRON LETT , 32 (45) 6649 - 6652.

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Abstract

Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy. The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.

Type: Article
Title: SAMARIUM(II) IODIDE PROMOTED RADICAL RING-OPENING REACTIONS OF CYCLOPROPYL KETONES
Keywords: SAMARIUM(II) IODIDE REDUCTION, CYCLOPROPYLCARBINYL RADICAL REARRANGEMENT, CYCLOPROPYL KETONE, RADICAL CYCLIZATION, SAMARIUM ENOLATE, ORGANIC-SYNTHESIS, CHAIN REACTIONS, CYCLIZATION, LANTHANIDES, CHEMISTRY, DESIGN
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/98247
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