Ioannou, M and Porter, MJ and Saez, F (2002) A ring expansion reaction of 1,3-oxathiolanes. CHEM COMMUN (4) 346 - 347.
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Abstract
1,3-Oxathiolanes are efficiently converted, via sulfur ylide intermediates, to 1,4-oxathianes by ring expansion with a silylated diazoacetate in the presence of a copper catalyst.
| Type: | Article |
|---|---|
| Title: | A ring expansion reaction of 1,3-oxathiolanes |
| Keywords: | REARRANGEMENT, TRIMETHYLSILYLDIAZOMETHANE, TAGETITOXIN |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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