Anderson, JC and Bou-Moreno, R (2010) The efficient synthesis of carbodiimides using a titanium imido complex. TETRAHEDRON , 66 (47) 9182 - 9186. 10.1016/j.tet.2010.09.073.
Full text not available from this repository.
Abstract
An efficient it synthesis of carbodiimides or ureas from the combination of a titanium imido complex 2 and a range of 12 aryl and aliphatic isocyanates is described Control experiments suggest that carbodimide formation is via heterocumulene metathesis through a transient intermediate eta(2)-ureato-N O metallacycle 8 (C) 2010 Elsevier Ltd All rights reserved
| Type: | Article |
|---|---|
| Title: | The efficient synthesis of carbodiimides using a titanium imido complex |
| DOI: | 10.1016/j.tet.2010.09.073 |
| Keywords: | Imido, Titanium, Carbodiimide, Urea, Isocyanate, Heterocumulene metathesis, REACTIVITY, CATALYSTS, AMINES, OXO, CYCLOADDITION, LIGANDS, ISOCYANATES, DERIVATIVES, CONVERSION, ZIRCONIUM |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
Archive Staff Only: edit this record