UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2NEt2)(2)}(n)] and [M{S2CN(CH2CH2CH2NMe2)(2)}(n)] (n=2, M = Ni, Cu, Zn, Pd; n=3, M = Co)

Hogarth, G; Rainford-Brent, EJCRCR; Kabir, SE; Richards, I; Wilton-Ely, JDET; Zhang, Q; (2009) Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2NEt2)(2)}(n)] and [M{S2CN(CH2CH2CH2NMe2)(2)}(n)] (n=2, M = Ni, Cu, Zn, Pd; n=3, M = Co). INORG CHIM ACTA , 362 (6) 2020 - 2026. 10.1016/j.ica.2008.09.030.

Full text not available from this repository.

Abstract

The amine-functionalised dithiocarbamate salts K[S2CN(CH2CH2NEt2)(2)] and K[S2CN(CH2CH2CH2NMe2)(2)] have been prepared and used for the synthesis of a number of bis and tris-dithiocarbamate complexes. The molecular structures of five of these namely, [M{S2CN(CH2CH2NEt2)(2)}(2)] (M = Cu, Ni), [M{S2CN(CH2CH2CH2NMe2)(2)}(2)] (M = Cu, Pd) and [Co{S2CN(CH2CH2CH2NMe2)(2)}(3)], have been elucidated by X-ray crystallography. (C) 2008 Elsevier B.V. All rights reserved.

Type:Article
Title:Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2NEt2)(2)}(n)] and [M{S2CN(CH2CH2CH2NMe2)(2)}(n)] (n=2, M = Ni, Cu, Zn, Pd; n=3, M = Co)
DOI:10.1016/j.ica.2008.09.030
Keywords:Dithiocarbamate, Crystal structures, Amine, Functionalised, RAFT POLYMERIZATION, MACROCYCLES, TRANSITION, CRYPTANDS, CADMIUM, LIGANDS, EXAMPLE, GOLD, ZINC
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

Archive Staff Only: edit this record