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Some novel electron transfer mediated cascade ring-opening reactions of bicyclo[4.1.0]ketones

Batey, RA; Harling, JD; Motherwell, WB; (1996) Some novel electron transfer mediated cascade ring-opening reactions of bicyclo[4.1.0]ketones. In: TETRAHEDRON. (pp. 11421 - 11444). PERGAMON-ELSEVIER SCIENCE LTD

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Abstract

The radical ring-opening reactions of cyclopropyl ketones, mediated by samarium (II) iodide and other electron transfer agents are described. This strategy allows tandem rearrangement cyclisation reactions and the trapping of the resultant samarium (III) enolates by a variety of electrophiles, for the construction of complex bicyclic systems. Copyright (C) 1996 Elsevier Science Ltd

Type:Proceedings paper
Title:Some novel electron transfer mediated cascade ring-opening reactions of bicyclo[4.1.0]ketones
Event:1st International Symposium on Cascade Reactions
Location:LEEDS, ENGLAND
Dates:1994
Keywords:REARRANGEMENT-CYCLIZATION STRATEGY, O-STANNYL KETYLS, SAMARIUM(II) IODIDE, RADICAL REACTIONS, CYCLOPROPYL KETONES, ORGANIC-SYNTHESIS, ALPHA,BETA-EPOXY KETONES, SYSTEMS, REDUCTION, CLEAVAGE
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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