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TIN(IV)-MEDIATED STEREOSELECTIVE SYNTHESIS OF EPOXIDES WITH CONCOMITANT ALKYL PEROXIDE FORMATION

HURSTHOUSE, MB; KHAN, A; MARSON, CM; PORTER, RA; (1995) TIN(IV)-MEDIATED STEREOSELECTIVE SYNTHESIS OF EPOXIDES WITH CONCOMITANT ALKYL PEROXIDE FORMATION. TETRAHEDRON LETT , 36 (33) 5979 - 5982.

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Abstract

Epoxy alkyl peroxides are formed stereoselectively by the action of t-butyl hydroperoxide-SnCl4 upon allylic alcohols containing an amido group, and with reversal of the diastereoselectivity shown by the action of t-butyl hydroperoxide-VO(acac)(2) upon analogous carbocyclic alcohols.

Type:Article
Title:TIN(IV)-MEDIATED STEREOSELECTIVE SYNTHESIS OF EPOXIDES WITH CONCOMITANT ALKYL PEROXIDE FORMATION
Keywords:REARRANGEMENTS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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