HURSTHOUSE, MB and KHAN, A and MARSON, CM and PORTER, RA (1995) TIN(IV)-MEDIATED STEREOSELECTIVE SYNTHESIS OF EPOXIDES WITH CONCOMITANT ALKYL PEROXIDE FORMATION. TETRAHEDRON LETT , 36 (33) 5979 - 5982.
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Abstract
Epoxy alkyl peroxides are formed stereoselectively by the action of t-butyl hydroperoxide-SnCl4 upon allylic alcohols containing an amido group, and with reversal of the diastereoselectivity shown by the action of t-butyl hydroperoxide-VO(acac)(2) upon analogous carbocyclic alcohols.
| Type: | Article |
|---|---|
| Title: | TIN(IV)-MEDIATED STEREOSELECTIVE SYNTHESIS OF EPOXIDES WITH CONCOMITANT ALKYL PEROXIDE FORMATION |
| Keywords: | REARRANGEMENTS |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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