STEREOCONTROLLED SYNTHESES OF HYDROXYLATED TRICYCLIC SYSTEMS BY A NEW ANNULATION OF 2-CYCLOHEXEN-1-ONE.
5491 - 5506.
Tricyclic keto-diols have been synthesised by a three-step annulation procedure in which hydroxyenones, prepared by the coupling of 2-cyclohexen-1-one with aldehydes, are diastereoselectively epoxidised and the syn-epoxides cyclised with tin(IV) chloride. Kinetic resolution of the hydroxyenones was achieved by enantiomeric epoxidation.
|Title:||STEREOCONTROLLED SYNTHESES OF HYDROXYLATED TRICYCLIC SYSTEMS BY A NEW ANNULATION OF 2-CYCLOHEXEN-1-ONE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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