Anderson, JC and Flaherty, A (2000) Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes. J CHEM SOC PERK T 1 (18) 3025 - 3027.
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Abstract
The mild and high yielding protodesilylation of C-2 trialkylsilyl terminal alkenes can be effected via a hydroboration-Peterson elimination protocol or, in the case of the phenyldimethylsilyl analogues, a one pot procedure using t-BuOK-18-C-6-TBAF can be used.
| Type: | Article |
|---|---|
| Title: | Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes |
| Keywords: | AZA-<2,3>-WITTIG SIGMATROPIC REARRANGEMENT, SILICON, CLEAVAGE, SILYLATION, SILANES, AMIDES, BOND |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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