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Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes

Anderson, JC; Flaherty, A; (2000) Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes. J CHEM SOC PERK T 1 (18) 3025 - 3027.

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Abstract

The mild and high yielding protodesilylation of C-2 trialkylsilyl terminal alkenes can be effected via a hydroboration-Peterson elimination protocol or, in the case of the phenyldimethylsilyl analogues, a one pot procedure using t-BuOK-18-C-6-TBAF can be used.

Type:Article
Title:Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes
Keywords:AZA-<2,3>-WITTIG SIGMATROPIC REARRANGEMENT, SILICON, CLEAVAGE, SILYLATION, SILANES, AMIDES, BOND
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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