COOMBES, RG; DIGGLE, AW; KEMPSELL, SP; (1993) THE MECHANISM OF NITRATION OF 2,4,6-TRIALKYLPHENOLS BY NITROGEN-DIOXIDE IN SOLUTION. TETRAHEDRON LETT , 34 (52) 8557 - 8560.
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The apparent rate of reaction of 2,4,6-trialkylphenols with nitrogen dioxide in solution is that of a 6-nitrocyclohexa-2,4-dien-1-one to 4-nitrocyclohexa-2,5-dien-1-one isomerisation unless the 2- and 6-alkyl groups are sufficiently bulky when the rare limiting stage may involve reaction between the appropriate phenoxy radical and NO2.
|Title:||THE MECHANISM OF NITRATION OF 2,4,6-TRIALKYLPHENOLS BY NITROGEN-DIOXIDE IN SOLUTION|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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