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OBSERVATIONS ON THE REACTION OF DITHIOKETALS WITH PARA-IODOTOLUENE DIFLUORIDE - A NOVEL ROUTE TO GEM-DIFLUORO COMPOUNDS

MOTHERWELL, WB; WILKINSON, JA; (1991) OBSERVATIONS ON THE REACTION OF DITHIOKETALS WITH PARA-IODOTOLUENE DIFLUORIDE - A NOVEL ROUTE TO GEM-DIFLUORO COMPOUNDS. SYNLETT (3) 191 - 192.

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Abstract

Reaction of dithioketals with 4-methyliodobenzene difluoride [4-(difluoroiodo)toluene] provides a simple, mild, and convenient method for conversion to the corresponding gemdifluoro compounds. The method is particularly suited to substrates which involve stabilised carbocationic intermediates.

Type:Article
Title:OBSERVATIONS ON THE REACTION OF DITHIOKETALS WITH PARA-IODOTOLUENE DIFLUORIDE - A NOVEL ROUTE TO GEM-DIFLUORO COMPOUNDS
Keywords:SYNTHETIC METHODS, FLUORINATION, ALDEHYDES, FLUORIDE, KETONES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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