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A NEW ROUTE TO ENOLATE ANION CHEMISTRY

EDWARDS, GL; MOTHERWELL, WB; POWELL, DM; SANDHAM, DA; (1991) A NEW ROUTE TO ENOLATE ANION CHEMISTRY. J CHEM SOC CHEM COMM (19) 1399 - 1401.

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Abstract

The direct conversion of an allylic alcohol to an alpha-alkylated carbonyl derivative may be achieved in a one-pot sequence via rhodium promoted isomerization of the derived lithium alkoxide or potassium triethylboronate complex.

Type:Article
Title:A NEW ROUTE TO ENOLATE ANION CHEMISTRY
Keywords:ALDOL CONDENSATION, ISOMERIZATION, COMPLEXES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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