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AN IMPROVED PREPARATION OF DIPHENYLMETHYLENECYCLOPROPANES AND THEIR USE IN INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS

LEWIS, RT; MOTHERWELL, WB; SHIPMAN, M; SLAWIN, AMZ; WILLIAMS, DJ; (1995) AN IMPROVED PREPARATION OF DIPHENYLMETHYLENECYCLOPROPANES AND THEIR USE IN INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS. TETRAHEDRON , 51 (11) 3289 - 3302.

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Abstract

The synthesis and intramolecular palladium catalysed cycloaddition reactions of diphenylmethylenecyclopropanes 1 and 2 containing olefinic and acetylenic acceptors are described This strategy provides a useful entry into some highly functionalised bicyclo[3.3.0]octane systems.

Type:Article
Title:AN IMPROVED PREPARATION OF DIPHENYLMETHYLENECYCLOPROPANES AND THEIR USE IN INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS
Keywords:OLEFINS, METHYLENECYCLOPROPANES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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