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OBSERVATIONS ON THE REACTION OF O-ACYLTHIOHYDROXAMATES WITH THIONITRITE ESTERS - A NOVEL FREE-RADICAL CHAIN-REACTION FOR DECARBOXYLATIVE AMINATION

GIRARD, P; GUILLOT, N; MOTHERWELL, WB; POTIER, P; (1995) OBSERVATIONS ON THE REACTION OF O-ACYLTHIOHYDROXAMATES WITH THIONITRITE ESTERS - A NOVEL FREE-RADICAL CHAIN-REACTION FOR DECARBOXYLATIVE AMINATION. J CHEM SOC CHEM COMM (23) 2385 - 2386.

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Abstract

Treatment of primary and secondary O-acyl derivatives of N-hydroxy-2-thiopyridone with thionitrite esters gives trans nitroso dimers in a free radical chain reaction.

Type:Article
Title:OBSERVATIONS ON THE REACTION OF O-ACYLTHIOHYDROXAMATES WITH THIONITRITE ESTERS - A NOVEL FREE-RADICAL CHAIN-REACTION FOR DECARBOXYLATIVE AMINATION
Keywords:CARBON RADICALS, GENERATION
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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