UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

Stereochemical aspects of intramolecular palladium catalysed [3+2] cycloadditions of methylenecyclopropanes

Corlay, H; Motherwell, WB; Pennell, AMK; Shipman, M; Slawin, AMZ; Williams, DJ; Binger, P; (1996) Stereochemical aspects of intramolecular palladium catalysed [3+2] cycloadditions of methylenecyclopropanes. TETRAHEDRON , 52 (13) 4883 - 4902.

Full text not available from this repository.

Abstract

The preparation and intramolecular palladium catalysed [3+2] cycloaddition reactions of a range of substrates containing either stereochemically defined 2,3-disubstituted methylenecyclopropanes 3 or acrylate accepters 12-15 are described. Evidence is presented which supports the hypothesis that these cycloaddition reactions proceed via palladium-trimethylenemethane type intermediates and that the two carbon-carbon bonds are formed in a highly asynchronous manner.

Type: Article
Title: Stereochemical aspects of intramolecular palladium catalysed [3+2] cycloadditions of methylenecyclopropanes
Keywords: CYCLO-ADDITION
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/74533
Downloads since deposit
0Downloads
Download activity - last month
Download activity - last 12 months
Downloads by country - last 12 months

Archive Staff Only

View Item View Item