Motherwell, WB (2002) Curiosity and simplicity in the invention and discovery of new metal-mediated reactions for organic synthesis. PURE AND APPLIED CHEMISTRY , 74 (1) 135 - 142.
Full text not available from this repository.
Abstract
Two organometallic themes of current interest are presented. The scope and generality of the reductive deoxygenation of carbonyl compounds to organozinc carbenoids using zinc in combination with a silicon electrophile is discussed. Alkoxycyclopropanation can be achieved using orthoformates as substrates. Preliminary observations on the development of a rhodium-catalyzed tandem hydrosilylation-intramolecular aldol Sequence are discussed.
| Type: | Article |
|---|---|
| Title: | Curiosity and simplicity in the invention and discovery of new metal-mediated reactions for organic synthesis |
| Location: | TAIPEI, TAIWAN |
| Keywords: | REDUCTIVE ALDOL REACTION, ORGANOZINC CARBENOIDS, CARBONYL-COMPOUNDS, GENERATION, METHYLENECYCLOPROPANES, KETONES |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
Archive Staff Only: edit this record