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Studies towards the Taming of the 'Carbocation' in the Regioselective Ring Opening of Epoxides to Allylic Alcohols

Chapman, HA; Herbal, K; Motherwell, WB; (2010) Studies towards the Taming of the 'Carbocation' in the Regioselective Ring Opening of Epoxides to Allylic Alcohols. SYNLETT (4) 595 - 598. 10.1055/s-0029-1219373.

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Abstract

Regioselective isomerisation of epoxides to allylic alcohols can be achieved using p-toluenesulfonic acid in the presence of 1,3-dimethylimidazolidin-2-one.

Type:Article
Title:Studies towards the Taming of the 'Carbocation' in the Regioselective Ring Opening of Epoxides to Allylic Alcohols
DOI:10.1055/s-0029-1219373
Keywords:epoxide ring opening, allylic alcohols, isomerisation, ALPHA-PINENE, REAGENT, ACIDS, OXIDE
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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