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Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability

Redshaw, C; Jana, S; Shang, CX; Elsegood, MRJ; Lu, XS; Guo, ZX; (2010) Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability. ORGANOMETALLICS , 29 (22) 6129 - 6132. 10.1021/om100703c.

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Abstract

Three zinc carboxylate complexes, [(C6F5Zn)(4)-Zn(Ar-1)6]center dot 1.5 toluene, [(C6F5Zn)(4)Zn(Ar-2)(6)]center dot 2toluene, and [(Ar-3)(6)Zn-4(mu(4)-O)]center dot MeCN (where Ar-1 = 2-chlorobenzoic acid (1), Ar-2 = 2,4,6-trimethylbenzoic acid (2), and Ar-3 = 3-dimethylaminobenzoic acid (3)), have been prepared from the reaction of (C6F5)(2)Zn center dot toluene and the corresponding functionalized benzoic acid. Complexes 1-3 were structurally characterized and screened for hydrogen absorption (uptake <0.3 wt %).

Type:Article
Title:Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability
DOI:10.1021/om100703c
Keywords:METAL-ORGANIC FRAMEWORKS, INSERTION REACTIONS, ADSORPTION SITES, GAS-ADSORPTION, CARBON-DIOXIDE, NUMBERS, MOF-5
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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