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Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .2. Incubation and interpretation

Baldwin, JE and Adlington, RM and Marquess, DG and Pitt, AR and Porter, MJ and Russell, AT (1996) Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .2. Incubation and interpretation. TETRAHEDRON , 52 (7) 2537 - 2556.

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Abstract

Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by incubation of a series of cyclopropane-containing stereochemical probes.

Type:Article
Title:Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .2. Incubation and interpretation
Keywords:ISOPENICILLIN-N SYNTHASE, PROTECTING GROUPS, ALCOHOLS, ACIDS, PHENYLSELENOPHTHALIMIDE, REAGENT
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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