Baldwin, JE and Adlington, RM and Marquess, DG and Pitt, AR and Porter, MJ and Russell, AT (1996) Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .1. Synthesis of tripeptide probes. TETRAHEDRON , 52 (7) 2515 - 2536.
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Abstract
Synthesis of four LLD-ACV analogues, in which the valine residue has been replaced by an amino acid containing a stereospecifically deuterated cyclopropane ring, is described.
| Type: | Article |
|---|---|
| Title: | Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis .1. Synthesis of tripeptide probes |
| Keywords: | CYCLOPROPYLCARBINYL, ALCOHOLS, STEREOCHEMISTRY, CEPHALOSPORINS, ALLYLCARBINYL, ACID |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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