Plet, JRH; Sandhu, AK; Sehailia, M; Porter, MJ; (2009) Thieme Chemistry Journal Awardees - Where Are They Now? Approaches to Tagetitoxin and its Decarboxy Analogue from D-Glucose. SYNLETT (20) 3258 - 3262. 10.1055/s-0029-1218525.
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A fifteen-step route has been developed from 1,6-anhydro-beta-D-glucopyranose to a C-alkynyl glycoside precursor of decarboxytagetitoxin. Preparation of 1,6-anhydro-5-C-vinyl-beta-D-glucopyranose, a potential precursor of tagetitoxin, is also described.
|Title:||Thieme Chemistry Journal Awardees - Where Are They Now? Approaches to Tagetitoxin and its Decarboxy Analogue from D-Glucose|
|Keywords:||carbohydrates, natural products, stereoselective synthesis, alkynes, organometallic reagents, ACYLATION CATALYST, PURIFICATION, ALCOHOLS, SULFUR, CORE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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