Muncaster, G; Sankar, G; Catlow, CRA; Thomas, JM; Coles, SJ; Hursthouse, M; (2000) The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O. CHEM MATER , 12 (1) 16 - +.
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Crystal structure of (K5CoW12O40)-W-III. 20H(2)O is obtained from a detailed single-crystal study. The interatomic distance, in particular the Co(III)-O distance obtained from the present study is in close agreement with the Co K-edge EXAFS data of the title compound. This material will serve as a good model system for understanding the redox properties of microporous cobalt-substituted aluminophosphate catalysts, since the title compound is noted as a rare example of Co(III) in tetrahedral coordination.
|Title:||The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O|
|Keywords:||MOLECULAR-SIEVE, REDOX CENTERS, CATALYSTS, CYCLOHEXANE, CHEMISTRY, LEWIS|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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