Corma, A and Rey, F and Thomas, JM and Sankar, G and Greaves, GN and Cervilla, A and Llopis, E and Ribeira, A (1996) On the atomic environment and the mode of action of the catalytic centre in an intercalated oxo-molybdenum complex [MoO2{O2CC(S)Ph(2)}(2)](2-) for oxygen-transfer reactions. CHEM COMMUN (14) 1613 - 1614.
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Abstract
The title anion accommodated as a pillar in the interlamellar space of a Zn((II))Al-III double hydroxide (hydrotalcite-like) host is shown by X-ray absorption spectroscopy, supplemented by other studies, to possess three terminal Mo=O groups, in contrast to the two that exist in the dispersed, catalytically active anion.
| Type: | Article |
|---|---|
| Title: | On the atomic environment and the mode of action of the catalytic centre in an intercalated oxo-molybdenum complex [MoO2{O2CC(S)Ph(2)}(2)](2-) for oxygen-transfer reactions |
| Keywords: | DOUBLE HYDROXIDE HOST, TRANSFER MOLYBDOENZYMES, AIR OXIDATION, THIOLS, SITES |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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