SANKAR, G and ROBERTS, MA and THOMAS, JM and KULKARNI, GU and RANGAVITTAL, N and RAO, CNR (1995) PROBING THE STRUCTURAL-CHANGES IN THE PHASE-TRANSITIONS OF A BI2MOO6 CATALYST - THE NATURE OF THE INTERMEDIATE-TEMPERATURE PHASE. J SOLID STATE CHEM , 119 (1) 210 - 215.
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Abstract
The nature of the phase transitions of Bi2MoO6 has been investigated by the combined use of X-ray diffraction and Xray absorption spectroscopy. The distorted MoO6 octahedra in the low-temperature form are shown to undergo further distortion in the intermediate-temperature form before transforming to MoO4 tetrahedra in the high-temperature phase. (C) 1995 Academic Press, Inc.
| Type: | Article |
|---|---|
| Title: | PROBING THE STRUCTURAL-CHANGES IN THE PHASE-TRANSITIONS OF A BI2MOO6 CATALYST - THE NATURE OF THE INTERMEDIATE-TEMPERATURE PHASE |
| Keywords: | BISMUTH MOLYBDATES, IN-SITU, SELECTIVE OXIDATION, NEUTRON-DIFFRACTION, CRYSTAL-STRUCTURE, XRD, SPECTROSCOPY, OXIDE, RAMAN, EXAFS |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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