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PROBING THE STRUCTURAL-CHANGES IN THE PHASE-TRANSITIONS OF A BI2MOO6 CATALYST - THE NATURE OF THE INTERMEDIATE-TEMPERATURE PHASE

SANKAR, G; ROBERTS, MA; THOMAS, JM; KULKARNI, GU; RANGAVITTAL, N; RAO, CNR; (1995) PROBING THE STRUCTURAL-CHANGES IN THE PHASE-TRANSITIONS OF A BI2MOO6 CATALYST - THE NATURE OF THE INTERMEDIATE-TEMPERATURE PHASE. J SOLID STATE CHEM , 119 (1) 210 - 215.

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Abstract

The nature of the phase transitions of Bi2MoO6 has been investigated by the combined use of X-ray diffraction and Xray absorption spectroscopy. The distorted MoO6 octahedra in the low-temperature form are shown to undergo further distortion in the intermediate-temperature form before transforming to MoO4 tetrahedra in the high-temperature phase. (C) 1995 Academic Press, Inc.

Type: Article
Title: PROBING THE STRUCTURAL-CHANGES IN THE PHASE-TRANSITIONS OF A BI2MOO6 CATALYST - THE NATURE OF THE INTERMEDIATE-TEMPERATURE PHASE
Keywords: BISMUTH MOLYBDATES, IN-SITU, SELECTIVE OXIDATION, NEUTRON-DIFFRACTION, CRYSTAL-STRUCTURE, XRD, SPECTROSCOPY, OXIDE, RAMAN, EXAFS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/707230
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