Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters.
The introduction of fluorinated aryls at zinc in Zn4N8-type (and to a lesser extent Zn4N6O) cages led to enhanced H-2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.
|Title:||Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters|
|Keywords:||METAL-ORGANIC FRAMEWORKS, HYDROGEN ADSORPTION, GAS-ADSORPTION, ZINC ALKYLS, OXYGENATION, COMPLEX, STORAGE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
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