Redshaw, C and Jana, S and Shang, CX and Elsegood, MRJ and Lu, XS and Guo, ZX (2010) Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters. CHEM COMMUN , 46 (47) 9055 - 9057. 10.1039/c0cc03380d.
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The introduction of fluorinated aryls at zinc in Zn4N8-type (and to a lesser extent Zn4N6O) cages led to enhanced H-2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.
|Title:||Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters|
|Keywords:||METAL-ORGANIC FRAMEWORKS, HYDROGEN ADSORPTION, GAS-ADSORPTION, ZINC ALKYLS, OXYGENATION, COMPLEX, STORAGE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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