UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

In situ investigations of the polyoxometalate Trojan Horse compound K7Na[(W18O56)-O-VI(SO3)(2)(H2O)(2)]center dot 20H(2)O under high temperature and high pressure conditions

Cabrera, RQ; Long, D-L; Cronin, L; McMillan, PF; (2010) In situ investigations of the polyoxometalate Trojan Horse compound K7Na[(W18O56)-O-VI(SO3)(2)(H2O)(2)]center dot 20H(2)O under high temperature and high pressure conditions. CrystEngComm , 12 (9) pp. 2568-2572. 10.1039/c003388j.

Full text not available from this repository.

Abstract

We have used Raman and IR spectroscopy to study the oxidation reaction of sulfite groups in the unique polyoxometalate compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O with a structure related to the Wells–Dawson type in situ at high temperature and high pressure. The results give new insights into the unusual redox process that occurs in this compound with electrons and O2− ions transferred between the polyoxometalate cluster and SO32−/SO42− groups held within the cage in a process that has been termed the “Trojan Horse” effect.

Type: Article
Title: In situ investigations of the polyoxometalate Trojan Horse compound K7Na[(W18O56)-O-VI(SO3)(2)(H2O)(2)]center dot 20H(2)O under high temperature and high pressure conditions
DOI: 10.1039/c003388j
Publisher version: http://doi.org/10.1039/c003388j
Language: English
UCL classification: UCL > School of BEAMS
UCL > School of BEAMS > Faculty of Maths and Physical Sciences
URI: http://discovery.ucl.ac.uk/id/eprint/679861
Downloads since deposit
0Downloads
Download activity - last month
Download activity - last 12 months
Downloads by country - last 12 months

Archive Staff Only

View Item View Item