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Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes

Cora, F; Sankar, G; Catlow, CRA; Thomas, JM; (2002) Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes. CHEM COMMUN (7) 734 - 735. 10.1039/b110017c.

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Abstract

Combined in situ X- ray absorption spectroscopy measurements and quantum mechanical calculations yield a quantitative three- dimensional structure of the tetrahedrally coordinated Mn( III) active sites in MnAlPO catalysts.

Type:Article
Title:Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes
DOI:10.1039/b110017c
Keywords:X-RAY-ABSORPTION, STABILITY, OXIDATION, AIR
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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