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Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes

Cora, F; Sankar, G; Catlow, CRA; Thomas, JM; (2002) Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes. CHEM COMMUN (7) 734 - 735. 10.1039/b110017c.

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Abstract

Combined in situ X- ray absorption spectroscopy measurements and quantum mechanical calculations yield a quantitative three- dimensional structure of the tetrahedrally coordinated Mn( III) active sites in MnAlPO catalysts.

Type: Article
Title: Electronic state and three-dimensional structure of Mn(III) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes
DOI: 10.1039/b110017c
Keywords: X-RAY-ABSORPTION, STABILITY, OXIDATION, AIR
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/66816
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