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PREPARATION AND X-RAY STRUCTURE OF A NOVEL DELOCALIZED DIPHOSPHAZENE COMPLEX - [OS3(CO)11((CF3)2P=N=PPH3)]

ANG, HG; CAI, YM; KWIK, WL; LEONG, WK; TOCHER, DA; (1991) PREPARATION AND X-RAY STRUCTURE OF A NOVEL DELOCALIZED DIPHOSPHAZENE COMPLEX - [OS3(CO)11((CF3)2P=N=PPH3)]. POLYHEDRON , 10 (8) 881 - 882.

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Abstract

The title compound 1, obtained from the reaction of [Os3(CO)11(CH3CN)] with (CF3)2P-N=PPh3, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The P-N-P moiety is nearly linear and the two P-N bonds are equivalent.

Type:Article
Title:PREPARATION AND X-RAY STRUCTURE OF A NOVEL DELOCALIZED DIPHOSPHAZENE COMPLEX - [OS3(CO)11((CF3)2P=N=PPH3)]
Keywords:CRYSTAL
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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