Steed, JW and Tocher, DA and Rogers, RD (1996) Ruthenium-mediated cyclodimerisation of buta-1,3-diene. CHEM COMMUN (13) 1589 - 1590.
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Abstract
Treatment of solvated Ru2+ ions in acetone solution with a large excess of buta-1,3-diene results in the formation of the unusual cyclooctatriene/cyclooctadienyl complex [Ru(eta(6)-C8H10)(1-3: 5-6-eta-C8H11)](+) 1 derived from the cyclodimerisation and dehydrogenation of two pairs of butadiene molecules at the metal centre.
| Type: | Article |
|---|---|
| Title: | Ruthenium-mediated cyclodimerisation of buta-1,3-diene |
| Keywords: | COMPLEXES, POLYMERIZATION, ACTIVATION, CATALYST |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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