Steed, JW; Tocher, DA; Rogers, RD; (1996) Ruthenium-mediated cyclodimerisation of buta-1,3-diene. CHEM COMMUN (13) 1589 - 1590.
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Treatment of solvated Ru2+ ions in acetone solution with a large excess of buta-1,3-diene results in the formation of the unusual cyclooctatriene/cyclooctadienyl complex [Ru(eta(6)-C8H10)(1-3: 5-6-eta-C8H11)](+) 1 derived from the cyclodimerisation and dehydrogenation of two pairs of butadiene molecules at the metal centre.
|Title:||Ruthenium-mediated cyclodimerisation of buta-1,3-diene|
|Keywords:||COMPLEXES, POLYMERIZATION, ACTIVATION, CATALYST|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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