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Towards engineering crystals of ionic complexes. Control over the nuclearity of a cationic metal complex by non-coordinating anions

Patra, GK; Mostafa, G; Tocher, DA; Datta, D; (2000) Towards engineering crystals of ionic complexes. Control over the nuclearity of a cationic metal complex by non-coordinating anions. INORG CHEM COMMUN , 3 (2) 56 - 58.

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Abstract

In the reaction of Cu(CH3CO2)(2). H2O with diethylenetriamine in equimolar proportion in ethanol in the presence of a slight excess of NaX, the nuclearity of the product is found to depend on the size of the non-coordinating anion X-; the larger the anion, the lower the tendency of polymerisation in the counter cation. (C) 2000 Elsevier Science S.A. All rights reserved.

Type:Article
Title:Towards engineering crystals of ionic complexes. Control over the nuclearity of a cationic metal complex by non-coordinating anions
Keywords:crystal structures, copper(II) complexes, copper(II) dimer, acetato bridged complexes, RAY
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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