Towards engineering crystals of ionic complexes. Control over the nuclearity of a cationic metal complex by non-coordinating anions.
INORG CHEM COMMUN
56 - 58.
In the reaction of Cu(CH3CO2)(2). H2O with diethylenetriamine in equimolar proportion in ethanol in the presence of a slight excess of NaX, the nuclearity of the product is found to depend on the size of the non-coordinating anion X-; the larger the anion, the lower the tendency of polymerisation in the counter cation. (C) 2000 Elsevier Science S.A. All rights reserved.
|Title:||Towards engineering crystals of ionic complexes. Control over the nuclearity of a cationic metal complex by non-coordinating anions|
|Keywords:||crystal structures, copper(II) complexes, copper(II) dimer, acetato bridged complexes, RAY|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
Archive Staff Only