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Activation of tri(2-furyl)phosphine at a dirhenium centre: Formation of phosphido-bridged dirhenium complexes.
J ORGANOMET CHEM
2941 - 2948.
Reaction of tri(2-furyl) phosphine (PFu(3)) with [Re-2(CO)(10) (n)(NCMe)(n)] (n = 1, 2) at 40 degrees C gave the substituted complexes [Re-2(CO)(10) (n)(PFu(3))(n)] (1 and 2), the phosphines occupying axial position in all cases. Heating [Re-2(CO)(10)] and PFu(3) in refluxing xylene also gives 1 and 2 together with four phosphido-bridged complexes; [Re-2(CO)(8) (n)(PFu(3))(n)(mu-PFu(2))(mu-H)] (n = 0, 1, 2) (3-5) and [Re-2(CO)(6)(PFu(3))(2)(mu-PFu(2))(mu-Cl)] (6) resulting from phosphorus-carbon bond cleavage. A series of separate thermolysis experiments has allowed a detailed reaction pathway to be unambiguously established. A similar reaction between [Re-2(CO)(10)] and PFu(3) in refluxing chlorobenzene furnishes four complexes which include 1, 2, 6 and the new binuclear complex [Re-2(CO)(6)(eta(1)-C4H3O)(2)(mu-PFu(2))(2)] (7). All new complexes have been characterized by a combination of spectroscopic data and single crystal X-ray diffraction studies. (C) 2009 Published by Elsevier B.V.
|Title:||Activation of tri(2-furyl)phosphine at a dirhenium centre: Formation of phosphido-bridged dirhenium complexes|
|Keywords:||Rhenium, Carbonyl, Tri(2-furyl)phosphine, C-P bond cleavage, X-ray structures, SUBSTITUTION-REACTIONS, MOLECULAR-STRUCTURE, CARBONYL-COMPLEXES, TRIOSMIUM CLUSTERS, COUPLING REACTIONS, BOND ACTIVATION, ARYL HALIDES, SHORT BITE, REACTIVITY, LIGANDS|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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