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Tris(N,N-diethyldithiocarbamato-S,S')(thionitrosyl-N)molybdenum(III), [Mo(eta(2)-S(2)CNEt(2))(3)(NS)]

Coffey, TA; Forster, GD; Hogarth, G; (1996) Tris(N,N-diethyldithiocarbamato-S,S')(thionitrosyl-N)molybdenum(III), [Mo(eta(2)-S(2)CNEt(2))(3)(NS)]. ACTA CRYSTALLOGR C , 52 2157 - 2159.

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The structure of the title compound consists of a neutral [Mo(C5H10NS2)(3)(NS)] unit, with the ligands arranged in a distorted pentagonal bipyramidal configuration. The thionitrosyl ligand occupies an axial site, with an N-S bond length of 1.568 (4) Angstrom. At 2.6083 (14) Angstrom, the axial Mo-S bond is considerably elongated with respect to those in the pentagonal plane [average 2.509 (16) Angstrom].

Type: Article
Title: Tris(N,N-diethyldithiocarbamato-S,S')(thionitrosyl-N)molybdenum(III), [Mo(eta(2)-S(2)CNEt(2))(3)(NS)]
URI: http://discovery.ucl.ac.uk/id/eprint/60742
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