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METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)]

HOGARTH, G; MALLORS, RL; NORMAN, T; (1993) METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)]. J CHEM SOC CHEM COMM (23) 1721 - 1723.

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Abstract

Addition of 2 equiv. of [WCl2(Ph2PMO)4] to 1,3- or 1,4-phenylenediisocyanate results in rapid oxidative addition of isocyanate affording the bis(imido)phenylene bridged tungsten(iv) complexes 1,3- and 1,4-[{cis,trans-WCl2(Ph2PMe)2(CO))2(mu-NC6H4N)], respectively; both have been characterised by X-ray crystallography.

Type:Article
Title:METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)]
Keywords:COMPLEXES, CENTERS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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