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A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES

COFFEY, TA; FORSTER, GD; HOGARTH, G; SELLA, A; (1993) A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES. POLYHEDRON , 12 (22) 2741 - 2743.

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Abstract

Reaction of two equivalents of ArNCO (Ar = 2,6-(1)Pr2C6H3) with [MoO2(edtc)2] affords the bisimido complex [Mo(NAr)2(edtc)2] shown by crystallography to contain two linear imido ligands; this is in contrast to the parent complex [Mo(NPh)2(edtc)2] previously shown to contain both linear and bent imido groups.

Type:Article
Title:A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES
Keywords:ELECTRONIC-STRUCTURE, COMPLEXES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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