COFFEY, TA;
FORSTER, GD;
HOGARTH, G;
SELLA, A;
(1993)
A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES.
POLYHEDRON
, 12
(22)
2741 - 2743.
Abstract
Reaction of two equivalents of ArNCO (Ar = 2,6-(1)Pr2C6H3) with [MoO2(edtc)2] affords the bisimido complex [Mo(NAr)2(edtc)2] shown by crystallography to contain two linear imido ligands; this is in contrast to the parent complex [Mo(NPh)2(edtc)2] previously shown to contain both linear and bent imido groups.
| Type: | Article |
|---|---|
| Title: | A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES |
| Keywords: | ELECTRONIC-STRUCTURE, COMPLEXES |
| UCL classification: | UCL > Office of the President and Provost UCL > School of BEAMS |
| URI: | http://discovery.ucl.ac.uk/id/eprint/60542 |
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