COFFEY, TA and FORSTER, GD and HOGARTH, G and SELLA, A (1993) A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES. POLYHEDRON , 12 (22) 2741 - 2743.
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Abstract
Reaction of two equivalents of ArNCO (Ar = 2,6-(1)Pr2C6H3) with [MoO2(edtc)2] affords the bisimido complex [Mo(NAr)2(edtc)2] shown by crystallography to contain two linear imido ligands; this is in contrast to the parent complex [Mo(NPh)2(edtc)2] previously shown to contain both linear and bent imido groups.
| Type: | Article |
|---|---|
| Title: | A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES |
| Keywords: | ELECTRONIC-STRUCTURE, COMPLEXES |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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