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INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]

HOGARTH, G; SKORDALAKIS, E; (1993) INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]. J ORGANOMET CHEM , 458 (1-2) C8 - C9.

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Abstract

Heating a toluene solution of [CP2Ru2(CO)(mu-CO){mu-C(O)C(Ph)= C(Ph)}], 1, with phenylisothiocyanate affords [Cp2Ru2(CO)(mu-CO)-{mu-SC(Ph)=C(Ph)C(=NPh)}], 2, as a result of alkyne insertion into the carbon-sulfur bond of the isothiocyanate.

Type:Article
Title:INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]
Keywords:METAL, ISOCYANATES, CHEMISTRY, LIGANDS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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