HOGARTH, G and SKORDALAKIS, E (1993) INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]. J ORGANOMET CHEM , 458 (1-2) C8 - C9.
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Abstract
Heating a toluene solution of [CP2Ru2(CO)(mu-CO){mu-C(O)C(Ph)= C(Ph)}], 1, with phenylisothiocyanate affords [Cp2Ru2(CO)(mu-CO)-{mu-SC(Ph)=C(Ph)C(=NPh)}], 2, as a result of alkyne insertion into the carbon-sulfur bond of the isothiocyanate.
| Type: | Article |
|---|---|
| Title: | INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))] |
| Keywords: | METAL, ISOCYANATES, CHEMISTRY, LIGANDS |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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