COFFEY, TA and FORSTER, GD and HOGARTH, G (1993) DOUBLE SULFUR CARBON BOND-CLEAVAGE OF A DITHIOCARBAMATE LIGAND AT A MOLYBDENUM(VI) CENTER - SYNTHESIS AND X-RAY STRUCTURE OF THE DISULFUR COMPLEX [MO(NPH)(S2)(EDTC)2] (EDTC = S2CNET2). J CHEM SOC CHEM COMM (19) 1524 - 1525.
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Abstract
Reaction of 1 equiv. of PhNCO with [MoO2(edtc)2] leads to the isolation of [Mo(NPh)(S2)(edtc)2] formed as a result of oxo substitution and a double sulfur-carbon bond cleavage of the dithiocarbamate; a second product is dimeric (MoO(edtc)(mu-NPh)]2.
| Type: | Article |
|---|---|
| Title: | DOUBLE SULFUR CARBON BOND-CLEAVAGE OF A DITHIOCARBAMATE LIGAND AT A MOLYBDENUM(VI) CENTER - SYNTHESIS AND X-RAY STRUCTURE OF THE DISULFUR COMPLEX [MO(NPH)(S2)(EDTC)2] (EDTC = S2CNET2) |
| Keywords: | MOLECULAR-STRUCTURE, METAL, CRYSTAL |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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