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Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(NR)<sub>2</sub>] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(η<sup>2</sup>-S<sub>2</sub>)(N-2,6-Cl<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]

Coffey, TA; Hogarth, G; Redmond, SP; (2000) Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(NR)<sub>2</sub>] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(η<sup>2</sup>-S<sub>2</sub>)(N-2,6-Cl<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]. Inorganica Chimica Acta , 308 (1-2) 155 - 159.

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Abstract

Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(eta (2)- S2CNEt2)(2)(NR)(2)] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(eta (2)-S2CNEt2)(2)(eta (2)-S-2)(N-2,6-Cl2C6H3)]

Type:Article
Title:Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(NR)<sub>2</sub>] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(η<sup>2</sup>- S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub>(η<sup>2</sup>-S<sub>2</sub>)(N-2,6-Cl<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]
Additional information:Journal Article OCT 20 372BC Hogarth G Univ London Univ Coll, Dept Chem, 20 Gordon St, London WC1H 0AJ, England INORG CHIM ACTA
Keywords:BIS(CYCLOPENTADIENYL)TITANIUM, COMPLEX, COMPLEXES, CRYSTAL, CRYSTAL STRUCTURE, crystal structures, EDTC = S2CNET2, Hydrogen, IMIDO, LIGATION, molybdenum complexes, OXO, REACTIVITY, Structure, sulfido complexes, X-ray
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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