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A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE)

CARMALT, CJ; NORMAN, NC; ORPEN, AG; STRATFORD, SE; (1993) A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE). J ORGANOMET CHEM , 460 (2) C22 - C24.

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Abstract

The synthesis and structure of the cationic, four-coordinate, ten-electron bismuth(III) complex [BiPh(2)(HMPA)(2)](+) (HMPA = hexamethylphosphoramide) is reported. The coordination geometry around the bismuth centre is that of a trigonal bipyramid with one equatorial site vacant and with phenyls in the other equatorial positions and the HMPA ligands in axial sites.

Type: Article
Title: A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE)
Keywords: CRYSTAL-STRUCTURE, CHEMISTRY, ELEMENTS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/59942
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