CARMALT, CJ and NORMAN, NC and ORPEN, AG and STRATFORD, SE (1993) A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE). J ORGANOMET CHEM , 460 (2) C22 - C24.
Full text not available from this repository.
Abstract
The synthesis and structure of the cationic, four-coordinate, ten-electron bismuth(III) complex [BiPh(2)(HMPA)(2)](+) (HMPA = hexamethylphosphoramide) is reported. The coordination geometry around the bismuth centre is that of a trigonal bipyramid with one equatorial site vacant and with phenyls in the other equatorial positions and the HMPA ligands in axial sites.
| Type: | Article |
|---|---|
| Title: | A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE) |
| Keywords: | CRYSTAL-STRUCTURE, CHEMISTRY, ELEMENTS |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
Archive Staff Only: edit this record