UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE)

CARMALT, CJ; NORMAN, NC; ORPEN, AG; STRATFORD, SE; (1993) A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE). J ORGANOMET CHEM , 460 (2) C22 - C24.

Full text not available from this repository.

Abstract

The synthesis and structure of the cationic, four-coordinate, ten-electron bismuth(III) complex [BiPh(2)(HMPA)(2)](+) (HMPA = hexamethylphosphoramide) is reported. The coordination geometry around the bismuth centre is that of a trigonal bipyramid with one equatorial site vacant and with phenyls in the other equatorial positions and the HMPA ligands in axial sites.

Type:Article
Title:A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE)
Keywords:CRYSTAL-STRUCTURE, CHEMISTRY, ELEMENTS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

Archive Staff Only: edit this record