CARMALT, CJ and FARRUGIA, LJ and NORMAN, NC (1995) SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A POLYMERIC IODOBISMUTHATE ANION. Z NATURFORSCH B , 50 (11) 1591 - 1596.
Full text not available from this repository.
Abstract
The reaction between [CH2=C(C6H4-4-NO2)CH(2)NMe(3)]I and eight equivalents of BiI3 in thf (tetrahydrofuran) afforded, after work-up, dark red crystals of the compound [CH2=C(C6H4-4-NO2)CH(2)NMe(3)](n)[{Bi2I7}(n)], the structure of which was established by X-ray crystallography and shown to contain a polymeric iodobismuthate anion. An analogous reaction between [CH3(CH2)(2)COS(CH2)(2)N(CH3)(3)]I and eight equivalents of BiI3 afforded orange crystals of the compound [CH3(CH2)(2)COS(CH2)(2)N(CH3)(3)](4)[Bi4I16] which was shown by X-ray crystallography to contain the tetranuclear [Bi4I16](4-) anion.
| Type: | Article |
|---|---|
| Title: | SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A POLYMERIC IODOBISMUTHATE ANION |
| Keywords: | X-RAY, POLYMERIC IODOBISMUTHATE ANION |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
Archive Staff Only: edit this record