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SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A POLYMERIC IODOBISMUTHATE ANION

CARMALT, CJ; FARRUGIA, LJ; NORMAN, NC; (1995) SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A POLYMERIC IODOBISMUTHATE ANION. Z NATURFORSCH B , 50 (11) 1591 - 1596.

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Abstract

The reaction between [CH2=C(C6H4-4-NO2)CH(2)NMe(3)]I and eight equivalents of BiI3 in thf (tetrahydrofuran) afforded, after work-up, dark red crystals of the compound [CH2=C(C6H4-4-NO2)CH(2)NMe(3)](n)[{Bi2I7}(n)], the structure of which was established by X-ray crystallography and shown to contain a polymeric iodobismuthate anion. An analogous reaction between [CH3(CH2)(2)COS(CH2)(2)N(CH3)(3)]I and eight equivalents of BiI3 afforded orange crystals of the compound [CH3(CH2)(2)COS(CH2)(2)N(CH3)(3)](4)[Bi4I16] which was shown by X-ray crystallography to contain the tetranuclear [Bi4I16](4-) anion.

Type:Article
Title:SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A POLYMERIC IODOBISMUTHATE ANION
Keywords:X-RAY, POLYMERIC IODOBISMUTHATE ANION
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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