MARSON, CM and WALKER, AJ and PICKERING, J and HARPER, S and WRIGGLESWORTH, R and EDGE, SJ (1993) EFFICIENT ROUTES TO CYCLIC 2,3-EPOXYALCOHOLS FROM CYCLOALKENYL KETONES, VIA CYCLOALKENYL ALCOHOLS. TETRAHEDRON , 49 (45) 10317 - 10338.
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Abstract
The minimising of torsional strain and non-bonding interactions is proposed as the explanation of high diastereoselectivity observed in the epoxidation of cycloalkenyl alcohols. reported for twenty three examples. The resulting 2,3-epoxyalcohols are key intermediates in the synthesis of tricyclic 1, 2-diols and beta-hydroxy ketones
| Type: | Article |
|---|---|
| Title: | EFFICIENT ROUTES TO CYCLIC 2,3-EPOXYALCOHOLS FROM CYCLOALKENYL KETONES, VIA CYCLOALKENYL ALCOHOLS |
| Keywords: | SHARPLESS ASYMMETRIC EPOXIDATION, HYDROXYLATED TRICYCLIC SYSTEMS, STEREOCONTROLLED SYNTHESES, ALLYLIC ALCOHOLS, 2-CYCLOHEXEN-1-ONE, HYDROPEROXIDE, ANNULATION, CHAIN |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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