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SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES

MCGHEE, WD; SELLA, A; OHARE, D; CLOKE, FGN; MEHNERT, C; GREEN, MLH; (1993) SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES. J ORGANOMET CHEM , 459 (1-2) 125 - 130.

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Abstract

The synthesis of vanadium and molybdenum complexes derived from nitrogen-containing heterocyclic aromatic ligands are described. The first eta-pyrazine sandwich complex, [V(eta6-Me4pyrazine)2], has been prepared by metal vapour synthesis and crystallographically characterized. The synthesis of (Mo(eta6-2,6-lutidine)2] has been substantially improved, and provides a convenient starting material for the preparation of the new half-sandwich compounds [Mo(eta6-2,6-lutidine)(PMe3)3] and [Mo(eta6-2,6-lutidine)(eta3-allyl)Cl]2.

Type:Article
Title:SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES
Keywords:METAL
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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