MCGHEE, WD;
SELLA, A;
OHARE, D;
CLOKE, FGN;
MEHNERT, C;
GREEN, MLH;
(1993)
SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES.
J ORGANOMET CHEM
, 459
(1-2)
125 - 130.
Abstract
The synthesis of vanadium and molybdenum complexes derived from nitrogen-containing heterocyclic aromatic ligands are described. The first eta-pyrazine sandwich complex, [V(eta6-Me4pyrazine)2], has been prepared by metal vapour synthesis and crystallographically characterized. The synthesis of (Mo(eta6-2,6-lutidine)2] has been substantially improved, and provides a convenient starting material for the preparation of the new half-sandwich compounds [Mo(eta6-2,6-lutidine)(PMe3)3] and [Mo(eta6-2,6-lutidine)(eta3-allyl)Cl]2.
| Type: | Article |
|---|---|
| Title: | SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES |
| Keywords: | METAL |
| URI: | http://discovery.ucl.ac.uk/id/eprint/425972 |
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