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Thermodynamic and structural aspects of the polyamorphic transition in yttrium and other rare-earth aluminate liquids

Wilding, MC; McMillan, PF; Navrotsky, A; (2002) Thermodynamic and structural aspects of the polyamorphic transition in yttrium and other rare-earth aluminate liquids. Physica A: Statistical Mechanics and its Applications , 314 (1-4) pp. 379-390. 10.1016/S0378-4371(02)01045-2.

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Abstract

The thermodynamic and structural aspects of the polyamorphic transition in yttrium and other rare earth aluminate liquids were analyzed. This transition was seen as the nucleation and growth of a low density phase in a matrix of a higher density liquid when YO-AlO liquids were cooled below the liquidus. A combination of DSC and solution calorimetry was used to evaluate the energetic differences between the two liquid phases of yttrium-aluminates.

Type: Article
Title: Thermodynamic and structural aspects of the polyamorphic transition in yttrium and other rare-earth aluminate liquids
DOI: 10.1016/S0378-4371(02)01045-2
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/29621
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