The solvation properties of nitric oxide.
Journal of the Chemical Society, Perkin Transactions 2
2067 - 2070.
Literature values for the partition of nitric oxide between the gas phase and water and between the gas phase and organic solvents have been combined to yield water-solvent partition coefficients. Analysis of the gas-solvent and water-solvent partition coefficients using the solvation equations of Abraham shows that nitric oxide is only a very weak hydrogen-bond base. The various solvation descriptors of Abraham for nitric oxide can be obtained, and are shown to be similar to other inorganic gases; the descriptors can be used to predict a large number of physicochemical properties of nitric oxide. A key property of nitric oxide is the lipophilicity, as the water-octanol partition coefficient, that we calculate to be quite small at 0.74 (log P-oct), about the same as that for argon or nitrogen
|Title:||The solvation properties of nitric oxide|
|Additional information:||Journal Article 358HU Abraham MH Univ Coll London, Dept Chem, 20 Gordon St, London WC1H 0AJ, England J CHEM SOC PERKIN TRANS 2|
|Keywords:||analysis, ARGON, As, Brain, COEFFICIENTS, DESCRIPTORS, EQUATION, EQUATIONS, GASES, HYDROGEN-BOND, LIPOPHILICITY, nitric oxide, NITRIC-OXIDE, Nitrogen, Other, PARTITION, partition coefficient, PARTITION-COEFFICIENTS, PREDICTION, SKIN PERMEABILITY, SOLUBILITY, SOLVATION, solvation descriptors, solvation equations, Solvents, VALUES, VAPORS, Water|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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