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Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]

Deeming, AJ; Forth, CS; Hogarth, G; Markham, D; Prince, JO; Steed, JW; (2002) Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]. CHEM COMMUN (19) 2230 - 2231. 10.1039/b203611h.

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Abstract

Turnstile rotation is suppressed in the equatorially substituted cluster [Os-3(mu-H)(2)(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}] which was separated by HPLC into two diastereomers which do not interconvert at room temperature and epimerize only slowly at 90 degreesC.

Type: Article
Title: Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]
DOI: 10.1039/b203611h
Keywords: METAL, COMPLEXES, LIGAND
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/190307
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