Deeming, AJ and Forth, CS and Hogarth, G and Markham, D and Prince, JO and Steed, JW (2002) Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]. CHEM COMMUN (19) 2230 - 2231. 10.1039/b203611h.
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Abstract
Turnstile rotation is suppressed in the equatorially substituted cluster [Os-3(mu-H)(2)(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}] which was separated by HPLC into two diastereomers which do not interconvert at room temperature and epimerize only slowly at 90 degreesC.
| Type: | Article |
|---|---|
| Title: | Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}] |
| DOI: | 10.1039/b203611h |
| Keywords: | METAL, COMPLEXES, LIGAND |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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