UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]

Deeming, AJ; Forth, CS; Hogarth, G; Markham, D; Prince, JO; Steed, JW; (2002) Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]. CHEM COMMUN (19) 2230 - 2231. 10.1039/b203611h.

Full text not available from this repository.

Abstract

Turnstile rotation is suppressed in the equatorially substituted cluster [Os-3(mu-H)(2)(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}] which was separated by HPLC into two diastereomers which do not interconvert at room temperature and epimerize only slowly at 90 degreesC.

Type:Article
Title:Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu(3)-S)(CO)(8){(S)-PhCHMeNH2}]
DOI:10.1039/b203611h
Keywords:METAL, COMPLEXES, LIGAND
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

Archive Staff Only: edit this record